Georgia lower Coastal Plain streams are characterized by low suspended load, low ionic strength, low pH, high PC02, dominance of Na-Cl over the more usual ca-Hco3-S04, relatively high proportions of Si02, AI, and Fe and high dissolved organic content. These characteristics become less pronounced in streams heading in the Piedmont and Fall Line. The chemistry of the streams is controlled by atmospheric input, weathering of the already strongly leached soils, and by the organic compounds produced on decay of vegetation in the low gradient, swampy terrain.
Principal Investigator: Kevin C. Beck (Georgia Institute of Technology)
Sponsor: GWRI
Start Date: 1968-07-01; Completion Date: 1971-09-30;
Keywords:
Description:
Georgia lower Coastal Plain streams are characterized by low suspended load, low ionic strength, low pH, high PC02, dominance of Na-Cl over the more usual ca-Hco3-S04, relatively high proportions of Si02, AI, and Fe and high dissolved organic content. These characteristics become less pronounced in streams heading in the Piedmont and Fall Line. The chemistry of the streams is controlled by atmospheric input, weathering of the already strongly leached soils, and by the organic compounds produced on decay of vegetation in the low gradient, swampy terrain. Hydrologic conditions, largely flushing of swamp waters into the streams after rains, control the relative importance of these factors.
The relatively high Cl content and constant ratios of Na, K, Mg, Ca, and S04 to Cl at values not far removed from sea water suggest that these species are derived from rain (concentrated by evaporation-transpiration) and atmospheric aerosols, and that mineral weathering contribution is minor. The relatively abundant AI, Fe, and Mn are significantly complexed by organic matter, and complexation is an important factor in solubilization and concentration in the streams. Their free ion activities can be related to equilibration with their hydroxides and oxyhydroxides through pH and Eh measurements, although Eh measurements are of doubtful validity. The dark brown color of the clear waters is due to dissolved organic matter; darker color is associated with higher contents of organic carbon, lower pH, and higher PCO2. The organic matter spontaneously settles in collection bottles and in the lower reaches of the streams. Additional flocculation occurs in the estuaries. Low levels of oxygen saturation are related to organic reaction. Silica decreases systematically downstream, as does pH. The correlation is due to addition of Si02-poor, organic-rich swamp waters. The stream waters lie in the stability field of kaolinite, and exchange sites in associated soils and sediments are occupied dominantly by H+ and hydroxy -Al. Unlike Piedmont and Fall Line streams, lower Coastal Plain streams have an inorganic anion deficiency; charge balance is attained by organic anions.
The stream chemistry departs markedly from that of the world average river and from almost all rivers previously described. However, many large tributaries of the Amazon and other low gradient tropical rivers, none of which have been studied extensively, are expected to show similar characteristics.
Estuaries of Coastal Plain streams normally exhibit simple river water-sea water mixing of major dissolved constituents, but with the introduction of low pH, low SiO2 waters by flushing of swamps during heavy rains silicate minerals in the estuary interact to modify water chemistry. The exact mechanism is unclear. Montmorillonite, with Mg++ as the dominant exchange cation, appears to be involved, either absorbing H+ and releasing Mg++ and Si02 to form kaolinite or dissolving incongruently. Estuarine levels of Al and Fe appear to be controlled by pH-dependent precipitation reactions in addition to mixing.